Home Categories Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium
A2392812

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium , 96% , 92390-26-6

Synonym(s):
1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η5-pentamethylcyclopentadienyl)ruthenium;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium;Cp*RuCl(cod)

CAS NO.:92390-26-6

Empirical Formula: C18H27ClRu5*

Molecular Weight: 379.93

MDL number: MFCD07369035

Pack Size Price Stock Quantity
250MG RMB959.20 In Stock
1G RMB2788.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 143-147℃
storage temp.  -20°C
color  brown microxtls
Stability: store cold
InChIKey JBVMVFXUVNUNNG-ONEVTFJLSA-M

Description and Uses

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

  • To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
  • To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
  • In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
  • To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
  • To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

Safety

Symbol(GHS) 
GHS02
Signal word  Danger
Hazard statements  H261
Precautionary statements  P231+P232-P422
Hazard Codes  F
Risk Statements  20/21/22-14/15
Safety Statements  22-36/37/39-43
RIDADR  UN 3395
WGK Germany  3
TSCA  No
HazardClass  4.3

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