Carbon disulfide , forHPLC,≥99.9% , 75-15-0
Synonym(s):
Carbon Bisulfide;Carbon Disulfide
CAS NO.：75-15-0
Empirical Formula: CS2
Molecular Weight: 76.14
MDL number: MFCD00011321
EINECS: 200-843-6
PRODUCT Properties
| Melting point: | -112--111 °C (lit.) |
| Boiling point: | 46 °C (lit.) |
| Density | 1.266 g/mL at 25 °C (lit.) |
| vapor density | 2.67 (vs air) |
| vapor pressure | 5.83 psi ( 20 °C) |
| refractive index | n |
| Flash point: | −29 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in alcohol, ether, benzene, oil, chloroform and carbon tetrachloride. |
| form | Liquid |
| Specific Gravity | 1.26 |
| color | ≤10(APHA) |
| Odor | Cabbage-like odor detectable at 0.016 to 0.42 ppm (mean = 0.2 ppm) |
| Relative polarity | 0.065 |
| explosive limit | 1-60%(V) |
| Odor Threshold | 0.21ppm |
| Water Solubility | 2.9 g/L (20 ºC) |
| FreezingPoint | -110.3℃ |
| λmax | λ: 386 nm Amax: ≤1.0 λ: 388 nm Amax: 0.50 λ: 394 nm Amax: 0.25 λ: 403 nm Amax: 0.10 λ: 410 nm Amax: 0.05 λ: 500-750 nm Amax: 0.01 |
| Merck | 14,1811 |
| BRN | 1098293 |
| Henry's Law Constant | 24.25 (atm?m3/mol) at 24 °C (Elliott, 1989) |
| Exposure limits | NIOSH REL: TWA 1 ppm, STEL 10 ppm, IDLH 500 ppm; OSHA
PEL: TWA 20 ppm, C 30 ppm; ACGIH TLV: TWA 10 ppm. |
| Dielectric constant | 2.6（Ambient） |
| Stability: | Stable. Extremely flammable. Highly volatile. Note low flash point and very wide explosion limits. Protect from heat, friction, shock, sunlight. Reacts violently with fluorine, azide solutions, zinc dust, liquid chlorine in the presence of iron. Incompatible with strong oxidizing agents, azides, aluminium, zinc, most common met |
| InChIKey | QGJOPFRUJISHPQ-UHFFFAOYSA-N |
| CAS DataBase Reference | 75-15-0(CAS DataBase Reference) |
| NIST Chemistry Reference | Carbon disulfide(75-15-0) |
| EPA Substance Registry System | Carbon disulfide (75-15-0) |
Description and Uses
For many years, carbon disulfide was manufactured by the reaction of charcoal with sulfur vapor at temperatures of 750– 1000 C, but by the mid-twentieth century, especially in the United States, the process was superseded by the reaction of natural gas (principally methane) with sulfur.
Carbon disulfide is used in the manufacture of regenerated cellulose rayon, cellophane, soil disinfectants, and electronicvacuum tubes. Other major uses are in theproduction of carbon tetrachloride, xanthates,thiocyanates, plywood adhesives, and rubberaccessories. It is also used as a solvent and asan eluant for organics adsorbed on charcoalin air analysis.
Safety
| Symbol(GHS) |    GHS02,GHS07,GHS08 |
| Signal word | Danger |
| Hazard statements | H225-H315-H319-H332-H361fd-H372 |
| Precautionary statements | P201-P210-P303+P361+P353-P304+P340+P312-P305+P351+P338-P308+P313 |
| Hazard Codes | F,T |
| Risk Statements | 11-36/38-48/23-62-63-39/23/24/25-23/24/25-48/20-40-36/37/38-19 |
| Safety Statements | 16-33-36/37-45-7-26 |
| OEB | B |
| OEL | TWA: 1 ppm (3 mg/m3), STEL: 10 ppm (30 mg/m3) [skin] |
| RIDADR | UN 1131 3/PG 1 |
| WGK Germany | 2 |
| RTECS | FF6650000 |
| Autoignition Temperature | 90 °C |
| TSCA | Yes |
| HS Code | 2813 10 00 |
| HazardClass | 3 |
| PackingGroup | I |
| Hazardous Substances Data | 75-15-0(Hazardous Substances Data) |
| Toxicity | LC50 inhal (rat) 25,000 mg/m3 (2 h) STEL (OSHA) 12 ppm (36 mg/m3)-skin PEL (OSHA) 4 ppm (12 mg/m3) TLV-TWA (ACGIH) 10 ppm (31 mg/m3)-skin |
| IDLA | 500 ppm |
