Home Categories 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
A1577712

2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane , 90% , 166330-03-6

CAS NO.:166330-03-6

Empirical Formula: C7H14BBrO2

Molecular Weight: 220.9

MDL number: MFCD09271779

Pack Size Price Stock Quantity
1G RMB134.40 In Stock
5G RMB399.20 In Stock
25g RMB1356.00 In Stock
100g RMB3823.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Boiling point: 68 °C / 6mmHg
Density  1.26
refractive index  1.4520-1.4560
Flash point: 62.8±22.6℃
storage temp.  Inert atmosphere,2-8°C
form  clear liquid
color  Colorless to Light orange to Yellow
InChI InChI=1S/C7H14BBrO2/c1-6(2)7(3,4)11-8(5-9)10-6/h5H2,1-4H3
InChIKey KBGMAXNDJAGTDD-UHFFFAOYSA-N
SMILES O1C(C)(C)C(C)(C)OB1CBr

Description and Uses

(Bromomethyl)boronic Acid Pinacol Ester, also known as 2-(Bromomethyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (BMTMD), is an organoboron compound extensively researched for its potential applications in organic synthesis and catalysis. It is a versatile reagent, exhibiting a broad range of reactivity suitable for various reactions, including Diels-Alder, Michael, and Wittig reactions. Moreover, BMTMD proves valuable as a catalyst in the synthesis of diverse compounds like heterocycles, amines, polymers (such as polyesters and polyamides), and organometallic compounds (including boronates, boronic esters, and boronic acids). Its ability to react with various functional groups, including carbonyl and carboxyl, facilitates nucleophilic addition and substitution mechanisms. Additionally, BMTMD can interact with amines, alcohols, and sulfonates, where nucleophilic addition and substitution mechanisms are involved depending on the functional group.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H227-H315-H319
Precautionary statements  P210-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P403+P235-P501
HS Code  2931900090

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