PRODUCT Properties
| Melting point: | 25°C |
| alpha | D20 -79.42° |
| Boiling point: | 228-229 °C (lit.) |
| Density | 0.922 g/mL at 25 °C (lit.) |
| vapor pressure | 26Pa at 25℃ |
| FEMA | 2668 | MENTHYL ACETATE (ISOMER UNSPECIFIED) |
| refractive index | n |
| Flash point: | 198 °F |
| storage temp. | -20°C |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | Oil |
| color | Colourless |
| Odor | at 100.00 %. tea minty fruity |
| Odor Type | mentholic |
| optical activity | -72.60 |
| Water Solubility | 17mg/L at 25℃ |
| JECFA Number | 431 |
| Merck | 13,5863 |
| LogP | 4 at 20℃ |
| CAS DataBase Reference | 89-48-5(CAS DataBase Reference) |
| NIST Chemistry Reference | Menthyl acetate(89-48-5) |
| EPA Substance Registry System | (+/-)-Menthyl acetate (89-48-5) |
Description and Uses
Menthyl acetate has a fresh odor similar to mint and rose (on dilution). It has a characteristic, fresh, pungent flavor, different from menthol (being much milder). It has a cool mouthfeel with only a trace of mint flavor. May be prepared by reacting acetic anhydride with menthol in the presence of anhydrous sodium acetate.
Menthyl acetate may be used in the preparation of 3-amino-2-hydroxyalkanoates via lithium amide-supported Mannich-type reaction of its lithium enolate with PMP-arylaldimines (PMP=p-methoxyphenyl) followed by in situ oxidation with oxaziridine.
