A1411612
1,2-Bis(diphenylphosphino)benzene , 98% , 13991-08-7
Synonym(s):
dppBz;dppbe;dppbenz;1,2-Bis(diphenylphosphanyl)benzene;dppben
| Pack Size | Price | Stock | Quantity |
| 250MG | RMB33.60 | In Stock |
|
| 1G | RMB75.20 | In Stock |
|
| 5G | RMB287.20 | In Stock |
|
| 25G | RMB1175.20 | In Stock |
|
| others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | 183-188 °C (lit.) |
| Boiling point: | 546.9±33.0 °C(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Fine Crystalline Powder |
| color | White |
| Water Solubility | Insoluble in water. |
| Sensitive | Air Sensitive |
| InChIKey | NFRYVRNCDXULEX-UHFFFAOYSA-N |
| CAS DataBase Reference | 13991-08-7(CAS DataBase Reference) |
Description and Uses
1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:
- As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
- In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
- As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
- As a ligand in the synthesis of alkenylboronates from acetylenic esters.
- To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.
Safety
| Symbol(GHS) |  GHS07 |
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P280g-P305+P351+P338 |
| Risk Statements | 36/37/38 |
| Safety Statements | 24/25 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 29319090 |
