Home Categories Organic Chemistry (±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate
A1330712

(±)-1,1'-Binaphthyl-2,2'-diyl Hydrogenphosphate , 99% , 35193-63-6

Synonym(s):
BNDHP

CAS NO.:35193-63-6

Empirical Formula: C20H13O4P

Molecular Weight: 348.29

MDL number: MFCD00010045

EINECS: 252-425-8

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5G RMB120.00 In Stock
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100G RMB879.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: ≥300 °C
Boiling point: 619.5±38.0 °C(Predicted)
Density  1.49±0.1 g/cm3(Predicted)
storage temp.  Sealed in dry,Room Temperature
form  Solid
pka 1.14±0.20(Predicted)
color  White to Yellow to Orange
Water Solubility  Extremely low soluble in water.
CAS DataBase Reference 35193-63-6(CAS DataBase Reference)

Description and Uses

1,1'-Binaphthyl-2,2'-diyl hydrogen phosphate, is used as a chiral chemical compound, a chiral ligand used in hydrocarboxylation reactions. Complexes with rhodium and mediates the asymmetric dipolar cycloaddition of diazo compounds. A number of racemic amines which have proven difficult to separate have been resolved with this chiral acid. Palladium derivatives have been used in asymmetric hydrocarboxylations, and rhodium derivatives have been used in dipolar cycloadditions.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi,Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  26-36-36/37/39-22
WGK Germany  3
RTECS  RZ2475100
10-23
HS Code  2931499090

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