Home Categories Analytical Chemistry Butyl ether
A1266712

Butyl ether , 99% , 142-96-1

Synonym(s):
Butyl ether;Dibutyl ether

CAS NO.:142-96-1

Empirical Formula: C8H18O

Molecular Weight: 130.23

MDL number: MFCD00009461

EINECS: 205-575-3

Update time: 2022-07-08

PRODUCT Properties

Melting point: -98 °C (lit.)
Boiling point: 142-143 °C (lit.)
Density  0.764 g/mL at 25 °C (lit.)
vapor density  4.48 (vs air)
vapor pressure  4.8 mm Hg ( 20 °C)
refractive index  n20/D 1.399(lit.)
Flash point: 77 °F
storage temp.  Store at <= 20°C.
solubility  H2O: soluble0.113g/L at 20°C
form  Liquid
color  Clear colorless
PH 5.2 (0.2g/l, H2O, 20℃)
Relative polarity 1.7
Odor Mild, ether-like.
PH Range 5.2
explosive limit 0.9-8.5%(V)
Water Solubility  0.03 g/100 mL (20 ºC)
Merck  14,1569
BRN  1732752
Dielectric constant 3.1(25℃)
Stability: Stable. Flammable. May form peroxides in storage. Incompatible with strong oxidizing agents.
InChIKey DURPTKYDGMDSBL-UHFFFAOYSA-N
LogP 3.35
CAS DataBase Reference 142-96-1(CAS DataBase Reference)
NIST Chemistry Reference n-Butyl ether(142-96-1)
EPA Substance Registry System Butyl ether (142-96-1)

Description and Uses

Butyl ether (dibutyl ether) is a colorless, stable liquid, with a mild ether-like odor. It is immiscible with water, with a specific gravity of 0.8, which is lighter than water. Butyl ether is a moderate fire risk and will form explosive peroxides on aging. Flammable range is 1.5%–7.6% in air, with a boiling point of 286°F (141°C) and a flash point of 77°F (25°C). Ignition temperature is 382°F (194°C), and the vapor density is 4.5, which is heavier than air. In addition to flammability, butyl ether is toxic on prolonged inhalation. The four-digit UN identification number is 1149. The NFPA 704 designation is health 2, flammability 3, and reactivity 1. The primary use is as a solvent.

Dibutyl ether is used mainly as a solvent for organic materials such as resins, oils, hydrocarbons, esters, gums, and alkaloids. It is also used as an extracting agent in metal separation, as a reacting medium in organic synthesis processes, and as a solvent in teaching, research and analytical laboratories.

Safety

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319-H335-H412
Precautionary statements  P210-P233-P240-P273-P303+P361+P353-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36/37/38-52/53
Safety Statements  61-24/25
RIDADR  UN 1149 3/PG 3
WGK Germany  2
RTECS  EK5425000
Autoignition Temperature 365 °F
Hazard Note  Irritant
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29091990
Hazardous Substances Data 142-96-1(Hazardous Substances Data)
Toxicity LD50 orally in rats: 7.4 g/kg (Smyth)

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