n-Butyl bromide , StandardforGC,>99.5%(GC) , 109-65-9
Synonym(s):
1-Bromobutane;Butyl bromide
CAS NO.:109-65-9
Empirical Formula: C4H9Br
Molecular Weight: 137.02
MDL number: MFCD00000260
EINECS: 203-691-9
PRODUCT Properties
Melting point: | -112 °C |
Boiling point: | 100-104 °C(lit.) |
Density | 1.276 g/mL at 25 °C(lit.) |
vapor density | 4.7 (vs air) |
vapor pressure | 150 mm Hg ( 50 °C) |
refractive index | n |
Flash point: | 23 °C |
storage temp. | Store below +30°C. |
solubility | 0.6g/l |
form | Liquid |
color | Clear colorless to light yellow |
Odor | characteristic odor |
explosive limit | 2.8-6.6%, 100°F |
Water Solubility | 0.608 g/L (30 ºC) |
Merck | 14,1553 |
BRN | 1098260 |
Dielectric constant | 7.1600000000000001 |
Stability: | Stable. Flammable - note low flash point. Incompatible with strong oxidizing agents, strong bases. |
InChIKey | MPPPKRYCTPRNTB-UHFFFAOYSA-N |
LogP | 2.75 |
Description and Uses
Butyl bromide is a highly flammable, colorlessliquid with a pleasant odor. Molecular weight = 137.04.Boiling point =101.6℃; Specific gravity (H2O:1) = 1.276at 20℃; Freezing/Melting point = 2112.4; Vapor density(air 5 1) = 4.68; Flash point =18℃ (21℃ for sec-isomer).Autoigniton temperature = 265℃. Explosive limits:LEL =2.6% at 100℃; UEL =6.6% at 100℃. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 3, Reactivity 0. Insoluble in water.
1-Bromobutane is used as an intermediate in organic synthesis and as a solvent for cleaning and degreasing. It acts as an alkylating agent as well as to prepare organometallic compounds such as n-butyllithium. It is also involved in the synthesis of procaine and tetracaine. It reacts with magnesium metal to prepare the Grignard reagent, which is used to form carbon-carbon bonds.
Safety
Symbol(GHS) | GHS02,GHS07,GHS09 |
Signal word | Danger |
Hazard statements | H225-H315-H319-H335-H411 |
Precautionary statements | P210-P273-P302+P352-P305+P351+P338 |
Hazard Codes | F,Xi,N |
Risk Statements | 11-36/37/38-51/53-10 |
Safety Statements | 16-26-60-37/39 |
RIDADR | UN 1126 3/PG 2 |
WGK Germany | 2 |
RTECS | EJ6225000 |
Autoignition Temperature | 509 °F |
TSCA | Yes |
HazardClass | 3 |
PackingGroup | II |
HS Code | 29033036 |
Toxicity | LD50 orally in Rabbit: 2761 mg/kg |