Bromobenzene , AR,99% , 108-86-1
Synonym(s):
Bromobenzene;Phenyl bromide
CAS NO.：108-86-1
Empirical Formula: C6H5Br
Molecular Weight: 157.01
MDL number: MFCD00000055
EINECS: 203-623-8
PRODUCT Properties
| Melting point: | -31 °C |
| Boiling point: | 156 °C(lit.) |
| Density | 1.491 g/mL at 25 °C(lit.) |
| vapor density | 5.41 (vs air) |
| vapor pressure | 10 mm Hg ( 40 °C) |
| refractive index | n |
| Flash point: | 124 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene. |
| form | Liquid |
| color | Clear colorless to faintly yellow |
| Odor | pleasant smell |
| explosive limit | 0.5-2.5%(V) |
| Water Solubility | insoluble. <0.1 g/100 mL at 20.5 ºC |
| Merck | 14,1406 |
| BRN | 1236661 |
| Henry's Law Constant | 2.47 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997) |
| Dielectric constant | 5.4（20℃） |
| Stability: | Stable. Combustible. Incompatible with strong oxidizing agents. |
| InChIKey | QARVLSVVCXYDNA-UHFFFAOYSA-N |
| LogP | 3.14 at 25℃ |
Description and Uses
Bromobenzene is a flammable, clear, colorlessmobile liquid with a pleasant odor. Molecularweight=157.02. Specific gravity (H2O:1)=1.48; Boilingpoint=156℃; Freezing/Melting point=2 31℃; Flashpoint=51℃; Autoignition temperature=565℃. Explosivelimits in air: LEL=6%; UEL=36.5%[icsc]. HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 2, Reactivity 0. Very slightly soluble in water; solubility=0.04% at 25℃.
Bromobenzene is a colorless, flammable liquid with a density greater than water and with an aromatic odor. It is synthesized by the reaction of bromide with benzene in the presence of iron powder. It is used for organic synthesis, particularly in the production of the intermediate phenylmagnesium bromide. Bromobenzene is an additive to motor oils and used as a crystallizing solvent. It is used as an ingredient in the manufacture of phencyclidine, a recreational drug.
Safety
| Symbol(GHS) |    GHS02,GHS07,GHS09 |
| Signal word | Warning |
| Hazard statements | H226-H315-H411 |
| Precautionary statements | P210-P273-P302+P352 |
| Hazard Codes | Xi,N,F,T |
| Risk Statements | 10-38-51/53-39/23/24/25-23/24/25 |
| Safety Statements | 61-45-36/37 |
| RIDADR | UN 2514 3/PG 3 |
| WGK Germany | 2 |
| RTECS | CY9000000 |
| Autoignition Temperature | 565 °C |
| TSCA | Yes |
| HS Code | 2903 99 80 |
| HazardClass | 3 |
| PackingGroup | III |
| Toxicity | LD50 orally in Rabbit: 2383 mg/kg |
