Home Categories Pharmaceutical intermediates 2-<WBR>Amino-<WBR>3-<WBR>bromopyridine
A0937712

2-<WBR>Amino-<WBR>3-<WBR>bromopyridine , 97% , 13534-99-1

CAS NO.:13534-99-1

Empirical Formula: C5H5BrN2

Molecular Weight: 173.01

MDL number: MFCD03095187

EINECS: 629-620-5

Pack Size Price Stock Quantity
1g RMB36.00 In Stock
5G RMB86.40 In Stock
25G RMB316.00 In Stock
100g RMB1247.20 In Stock
500g RMB5599.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 63-67 °C
Boiling point: 232.0±20.0 °C(Predicted)
Density  1.6065 (rough estimate)
vapor pressure  0.83-1.8Pa at 20-25℃
refractive index  1.5182 (estimate)
storage temp.  Keep in dark place,Inert atmosphere,Room temperature
pka 4.14±0.36(Predicted)
form  Powder
color  Gray to brown
BRN  109867
LogP 1.5 at 20℃ and pH7

Description and Uses

2-Amino-3-bromopyridine may be used to synthesize:

  • 2-acylamido-3-bromopyridines
  • 2-anilino-3-bromopyridine
  • 3-[(2-methoxyphenyl)ethynyl]pyridin-2-amine
  • 3-[(4-methoxyphenyl)ethynyl]pyridin-2-amine
  • N-(bromopyridyl)amidines
  • carbolines via palladium catalyzed arylation followed by palladium catalyzed amination reaction
  • 2-amino-3-cyanopyridine via palladium catalyzed cyanation reaction with potassium ferro-cyanide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene [DBU]
  • nitro-substituted N,N′-dipyridinylamines via palladium catalyzed coupling reaction with 2-chloro-3-nitropyridine in the presence of Xantphos ligand
  • 2-amino-3-iodopyridine via reaction with sodium iodide in the presence of copper(I)iodide and trans-N,N′-dimethylcyclohexane-1,2-diamine

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HazardClass  IRRITANT
PackingGroup  II
HS Code  29333990

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