t-Butyldichlorophosphine , 98% , 25979-07-1

Synonym(s):
(1,1-Dimethylethyl)phosphonous dichloride solution;tert-Butylphosphine dichloride;tert-Butylphosphonous dichloride

CAS NO.：25979-07-1

Empirical Formula: C4H9Cl2P

Molecular Weight: 158.99

MDL number: MFCD00013615

EINECS: 247-386-9

PRODUCT Properties

• Melting point: 44-49 °C(lit.)
• Boiling point: 142-150 °C
• Density: 0.766 g/mL at 25 °C
• storage temp.: Inert atmosphere,2-8°C
• form: Low Melting Crystalline Mass
• color: White to light yellow
• Water Solubility: Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents.
• Sensitive: Air Sensitive
• Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
• CAS DataBase Reference: 25979-07-1(CAS DataBase Reference)
• NIST Chemistry Reference: Tert-butyldichlorophosphine(25979-07-1)

Description and Uses

Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions.

Safety

• Symbol(GHS): GHS05
• Signal word: Danger
• Hazard statements: H314
• Precautionary statements: P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
• Hazard Codes: C,T,F
• Risk Statements: 14-34-29-23/24/25-17-11-67-22-19
• Safety Statements: 26-27-28-36/37/39-45-8-16
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• TSCA: No
• HazardClass: 8
• PackingGroup: II
• HS Code: 29310099