Home Categories Organic Chemistry Trirutheniumdodecacarbonyl
A0743456

Trirutheniumdodecacarbonyl , 99.95%metalsbasis , 15243-33-1

Synonym(s):
Ruthenium carbonyl;tri-Ruthenium dodecacarbonyl

CAS NO.:15243-33-1

Empirical Formula: C12O12Ru3

Molecular Weight: 639.33

MDL number: MFCD00011209

EINECS: 239-287-4

Pack Size Price Stock Quantity
1g RMB751.20 In Stock
5g RMB3191.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 150 °C
storage temp.  Inert atmosphere,Room Temperature
solubility  Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone.
form  crystal
color  orange
CAS DataBase Reference 15243-33-1(CAS DataBase Reference)
EPA Substance Registry System Ruthenium, dodecacarbonyltri-, triangulo (15243-33-1)

Description and Uses

Triruthenium dodecacarbonyl is a metal carbonyl complex, classified as an inorganic compound. Its molecular formula is Ru3(CO)12, with a molecular weight of 639.33. It possesses D3h symmetry and a core composed of a Ru equilateral triangle. Each Ru atom is attached to two axial and two equatorial CO ligands. Unlike triiron dodecacarbonyl, this compound does not contain any bridge bonds. It is commonly employed as a precursor for various organoruthenium compounds.

Ruthenium carbonyl is a H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H332
Precautionary statements  P261-P271-P304+P340+P312
Hazard Codes  F,Xn
Risk Statements  11-20-2017/11/20
Safety Statements  24/25
RIDADR  1325
WGK Germany  3
Hazard Note  Flammable/Harmful
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  28439000

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