A0743312
(S)-(-)-2-Amino-2'-hydroxy-1,1'-binaphthyl , 98% , 137848-29-4
Synonym(s):
(S)-(−)-2-Amino-2′-hydroxy-1,1′-binaphthalene;(S)-NOBIN
Pack Size | Price | Stock | Quantity |
100MG | RMB421.60 | In Stock |
|
500MG | RMB1684.80 | In Stock |
|
others | Enquire |
Update time: 2022-07-08
PRODUCT Properties
Melting point: | 171.0 to 175.0 °C |
Boiling point: | 471.5±30.0 °C(Predicted) |
Density | 1.275 |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
form | powder to crystal |
pka | 8.90±0.50(Predicted) |
color | White to Light red to Green |
CAS DataBase Reference | 137848-29-4(CAS DataBase Reference) |
Description and Uses
(S)-(-)-2′-Amino-1,1′-binaphthalen-2-ol or (S)-NOBIN, is a non-symmetrically substituted 1,1′-binaphthalene ligand. It can be used as a catalyst in the asymmetric synthesis of unnatural α-alkyl amino acids by phase-transfer catalysis (PTC). (S)-NOBIN can also be employed as starting material to prepare N-monoalkyl and N,N-dialkyl (S)-NOBIN analogs by reacting with aldehydes via reductive amination reaction. N-monoaryl derivatives are obtained from NOBIN via Hartwig?Buchwald arylation reaction.
Safety
Symbol(GHS) | GHS05,GHS09 |
Signal word | Danger |
Hazard statements | H318-H410 |
Precautionary statements | P273-P280-P305+P351+P338-P501 |
Hazard Codes | Xi,N |
Risk Statements | 36/37/38-50/53-41 |
Safety Statements | 26-36/37/39-61-60-39 |
RIDADR | UN 3077 9 / PGIII |
WGK Germany | 3 |
HS Code | 29222990 |