Home Categories Organic Chemistry (Acetylacetonato)dicarbonylrhodium(I)
A0727112

(Acetylacetonato)dicarbonylrhodium(I) , 99% , 14874-82-9

Synonym(s):
(Acetylacetonato)dicarbonylrhodium(I);Dicarbonyl-acetylacetonato-rhodium(I);Dicarbonylrhodium(I) 2,4-pentanedionate;Rh(CO)2acac;Rhodium(I) dicarbonyl acetylacetonate

CAS NO.:14874-82-9

Empirical Formula: C7H7O4Rh

Molecular Weight: 258.03

MDL number: MFCD00009884

EINECS: 238-947-9

Pack Size Price Stock Quantity
250MG RMB2159.20 In Stock
500MG RMB3439.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 154-156 °C (lit.)
Density  1.96[at 20℃]
vapor pressure  0.13Pa at 25℃
storage temp.  Inert atmosphere,Room Temperature
solubility  Soluble in acetone
form  Needles or Flakes
color  Greenish-red
Water Solubility  insoluble
Exposure limits ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
LogP 0.4 at 20℃
NIST Chemistry Reference Rhodium, dicarbonyl(2,4-pentanedionato-o,o')-, (sp-4-2)-(14874-82-9)
EPA Substance Registry System Rhodium, dicarbonyl(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (SP-4-2)- (14874-82-9)

Description and Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

Catalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds

Safety

Symbol(GHS) 
GHS02,GHS07
Signal word  Warning
Hazard statements  H228-H317-H319
Precautionary statements  P210-P240-P241-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,F,T
Risk Statements  36/37/38-44-43-25
Safety Statements  26-37/39-45-36/37/39-24/25
RIDADR  3282
WGK Germany  3
TSCA  No
HazardClass  6.1
PackingGroup  III
HS Code  28439000

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