PRODUCT Properties
Melting point: | 52 °C |
Boiling point: | 302 °C(lit.) |
Density | 1.16 |
vapor density | 5.82 (vs air) |
vapor pressure | 1 mm Hg ( 108 °C) |
refractive index | 1.5785 (estimate) |
Flash point: | 307 °F |
storage temp. | Store below +30°C. |
solubility | alcohol: passes test |
form | crystalline |
pka | 0.79(at 25℃) |
color | tan |
Odor | Floral odor |
Water Solubility | Slightly soluble. 0.03 g/100 mL |
Sensitive | Air & Light Sensitive |
Merck | 14,3317 |
BRN | 508755 |
Exposure limits | TLV-TWA 10 mg/m3 (ACGIH and MSHA). |
Dielectric constant | 3.3(11℃) |
Stability: | Stable; may discolour on exposure to light. Incompatible with strong acids, strong oxidizing agents. |
LogP | 3.82 at 20.2℃ |
Description and Uses
Solutions of diphenylamine are used to treat apples a few days before harvest. Residue on apples’ surfaces of 10 ppm is permitted by regulation in Australia, Canada, and the United States.
Diphenylamine is used post-harvest to prevent superficial scald in apples in cold store.
Safety
Symbol(GHS) | GHS06,GHS08,GHS09 |
Signal word | Danger |
Hazard statements | H301+H311+H331-H373-H410 |
Precautionary statements | P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P314 |
Hazard Codes | T,N,F |
Risk Statements | 23/24/25-33-50/53-52/53-39/23/24/25-11-51/53 |
Safety Statements | 28-36/37-45-60-61-28A-16-7 |
RIDADR | UN 3077 9/PG 3 |
OEB | B |
OEL | TWA: 10 mg/m3 |
WGK Germany | 3 |
RTECS | JJ7800000 |
F | 8-10-23 |
Autoignition Temperature | 630 °C DIN 51794 |
TSCA | Yes |
HS Code | 2921 44 00 |
HazardClass | 6.1 |
PackingGroup | III |
Toxicity | LD50 orally in Rabbit: 1120 mg/kg LD50 dermal Rabbit > 5000 mg/kg |