A0659212
Allyl bromide , Including ≤1000ppm oxide acrylic stabilizer, 98% , 106-95-6
Synonym(s):
3-Bromo-1-propene;Allyl bromide
CAS NO.：106-95-6
Empirical Formula: C3H5Br
Molecular Weight: 120.98
MDL number: MFCD00000244
EINECS: 203-446-6
Update time: 2022-07-08
PRODUCT Properties
| Melting point: | -119 °C |
| Boiling point: | 70-71 °C(lit.) |
| Density | 1.398 g/mL at 25 °C(lit.) |
| vapor density | 4.2 (vs air) |
| vapor pressure | 18.66kPa at 25℃ |
| refractive index | n |
| Flash point: | 28 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Soluble) |
| form | Liquid |
| color | Clear colorless to slightly colored |
| Specific Gravity | 1.398 |
| Odor | unpleasant |
| explosive limit | 4.3-7.3%(V) |
| Water Solubility | insoluble |
| Sensitive | Light Sensitive |
| Merck | 14,288 |
| BRN | 605308 |
| Dielectric constant | 7.0 |
| Exposure limits | ACGIH: TWA 0.1 ppm; STEL 0.2 ppm (Skin) |
| Stability: | Stable. Flammable. Incompatible with strong oxidizing agents. |
| InChIKey | BHELZAPQIKSEDF-UHFFFAOYSA-N |
| LogP | 1.79 |
| CAS DataBase Reference | 106-95-6(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-Propene, 3-bromo-(106-95-6) |
| EPA Substance Registry System | 3-Bromopropene (106-95-6) |
Description and Uses
Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.
Safety
| Symbol(GHS) |      GHS02,GHS05,GHS06,GHS08,GHS09 |
| Signal word | Danger |
| Hazard statements | H225-H301+H331-H314-H340-H350-H400 |
| Precautionary statements | P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 |
| Hazard Codes | F,T,N |
| Risk Statements | 11-23/25-34-50-25-46-45 |
| Safety Statements | 16-26-36/37/39-45-60-61-53 |
| RIDADR | UN 1099 3/PG 1 |
| WGK Germany | 2 |
| RTECS | UC7090000 |
| F | 8-19 |
| Autoignition Temperature | 554 °F |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | I |
| HS Code | 29033036 |
| Hazardous Substances Data | 106-95-6(Hazardous Substances Data) |
| Toxicity | LD50 orally in Rabbit: 120 mg/kg |
