Acrolein diethyl acetal , 96% , 3054-95-3
Synonym(s):
3,3-Diethoxy-1-propene
CAS NO.：3054-95-3
Empirical Formula: C7H14O2
Molecular Weight: 130.18
MDL number: MFCD00009239
EINECS: 221-276-0
PRODUCT Properties
| Melting point: | 120-124 °C |
| Boiling point: | 125 °C (lit.) |
| Density | 0.854 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 40 °F |
| storage temp. | 2-8°C |
| solubility | Chloroform (Soluble), Ethyl Acetate (Slightly) |
| form | Liquid |
| color | Clear colorless |
| Water Solubility | Slightly soluble in water. |
| BRN | 1701567 |
| Stability: | Light sensitive |
| InChIKey | MCIPQLOKVXSHTD-UHFFFAOYSA-N |
| LogP | 1.560 |
| CAS DataBase Reference | 3054-95-3(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-Propene, 3,3-diethoxy-(3054-95-3) |
| EPA Substance Registry System | 1-Propene, 3,3-diethoxy- (3054-95-3) |
Description and Uses
3,3-Diethoxypropene is a colorless flammableliquid; Molecular weight=130.21; Boiling point=123.5℃;Flash point=4.4℃. Hazard Identification (based on HMISRating System scale: 0-4): Health 1, Flammability 3,Reactivity 1. Water solubility=not determined.
Acrolein diethyl acetal is widely used to carry out chemoselective Heck arylation to synthesize either 3-arylpropanoate esters or cinnamaldehyde derivatives.
It can also be used as one of the precursors to synthesize natural products like (?)-(Z)-Deoxypukalide, (?)-Laulimalide, botryodiplodin, neolaulimalide and isolaulimalide.
Safety
| Symbol(GHS) |   GHS02,GHS07 |
| Signal word | Danger |
| Hazard statements | H225-H319 |
| Precautionary statements | P210-P305+P351+P338 |
| Hazard Codes | F,Xi |
| Risk Statements | 11-36 |
| Safety Statements | 9-16-26-33-29-7/9 |
| RIDADR | UN 2374 3/PG 2 |
| WGK Germany | 3 |
| RTECS | AS1370000 |
| F | 8-13 |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29110000 |
