Home Categories Inorganic chemistry Ammonium formate
A0597112

Ammonium formate , Chromatography, ≥99.0% , 540-69-2

Synonym(s):
Formic acid ammonium salt

CAS NO.:540-69-2

Empirical Formula: CH5NO2

Molecular Weight: 63.06

MDL number: MFCD00013103

EINECS: 208-753-9

Pack Size Price Stock Quantity
1g RMB30.40 In Stock
5g RMB96.80 In Stock
50G RMB364.00 In Stock
250G RMB1464.80 In Stock
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Update time: 2022-07-08

PRODUCT Properties

Melting point: 119-121 °C (lit.)
Boiling point: 103.28°C (rough estimate)
Density  1.26 g/mL at 25 °C (lit.)
vapor pressure  0.033Pa at 25℃
refractive index  1.4164 (estimate)
Flash point: 104℃
storage temp.  Inert atmosphere,Room Temperature
solubility  H2O: 10 M at 20 °C, clear, colorless
form  Solid
color  White
PH 6.53(1 mM solution);6.5(10 mM solution);6.49(100 mM solution);6.45(1000 mM solution)
Odor Slight formic acid odour
PH Range 6 - 7
Water Solubility  soluble
Sensitive  Hygroscopic
λmax λ: 260 nm Amax: 0.05
λ: 280 nm Amax: 0.04
Merck  14,523
BRN  3625095
Stability: Stable. Hygroscopic. Incompatible with strong acids, strong oxidizing agents.
InChIKey VZTDIZULWFCMLS-UHFFFAOYSA-N
LogP -3.34 at 25℃
CAS DataBase Reference 540-69-2(CAS DataBase Reference)
EPA Substance Registry System Ammonium formate (540-69-2)

Description and Uses

Ammonium formate is widely used in various organic reactions like Leuckart reaction which involves the reductive amination of aldehydes and ketones. It serves as a buffer in high performance liquid chromatography (HPLC) and liquid chromatography-mass spectrometry (LC/MS). It finds application in palladium on carbon (Pd/C) reduction of functional groups. For example, reduction of alkenes to alkanes and formaldehyde to methanol. It is also used to prepare formic acid insitu as well as used to store formic acid by making it as an ammonium salt.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280-P305+P351+P338-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  2
RTECS  BQ6650000
3-10
TSCA  Yes
HS Code  29151200
Hazardous Substances Data 540-69-2(Hazardous Substances Data)
Toxicity LD50 orl-mus: 2250 mg/kg ZERNAL 9,332,69

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