Home Categories Inorganic chemistry Ammoniumsulfidesolution
A0565650

Ammoniumsulfidesolution , 20%-26%inH2O , 12135-76-1

CAS NO.:12135-76-1

Empirical Formula: H8N2S

Molecular Weight: 68.14

MDL number: MFCD00010892

EINECS: 235-223-4

Update time: 2022-07-08

PRODUCT Properties

Melting point: decomposes [HAW93]
Boiling point: 40 °C
Density  1 g/mL at 25 °C
vapor pressure  600 hPa at 20 °C
FEMA  2053 | AMMONIUM SULFIDE
refractive index  n20/D 1.467
Flash point: 90 °F
storage temp.  room temp
solubility  Very soluble in water, almost insoluble in alcohol and oils.
form  Liquid
pka 3.42±0.70(Predicted)
Specific Gravity 1.2
color  Yellow to orange
Odor Ammonia odour
PH Range 9.5 ( 45% aqueous solution)
explosive limit 4-46%
Odor Type sulfurous
Water Solubility  Miscible with water, alcohol and liquid ammonia.
Merck  13,560
Stability: Stable. Pure material is highly flammable - note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, copper, brass, bronze, strong bases, zinc, aluminium.
InChIKey UXXGWUQNRMPNKH-UHFFFAOYSA-N

Description and Uses

Ammonium sulfide solution is used occasionally in photographic developing, to apply patina to bronze, and in textile manufacturing. Ammonium sulfide is a very useful reagent in mineral analysis. Used in continuous culture of saccharomyces cerevisiae, useful in a double staining technique for visualization of astrocytes and microglia from brain sections and astroglial cell cultures. It plays an important role to modify the surface of low κ dielectric thin films. It is essential for molecular beam epitaxy regrowth. It is an unstable salt and acts as a selective reducing agent.

Safety

Symbol(GHS) 
GHS02,GHS05
Signal word  Danger
Hazard statements  H226-H314
Precautionary statements  P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C,N,F
Risk Statements  11-31-34-50-10
Safety Statements  26-36/37/39-45-61-16
RIDADR  UN 2683 8/PG 2
WGK Germany  -
10-13-23
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  28309090

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