Home Categories (4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III)Hexafluorophosphate
(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III)Hexafluorophosphate
SDS-US
A0527656

(4,4'-Di-tert-butyl-2,2'-bipyridine)bis[(2-pyridinyl)phenyl]iridium(III)Hexafluorophosphate , 99% , 676525-77-2

Synonym(s):
[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate;[Ir(dtbbpy)(ppy)2][PF6];Ir Photocatalyst

CAS NO.：676525-77-2

Empirical Formula: C40H40F6IrN4P

Molecular Weight: 913.97

MDL number: MFCD28369259

Pack Size Price Stock Quantity
100mg RMB367.20 In Stock
500mg RMB2599.20 In Stock
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Update time: 2022-07-08

PRODUCT Properties

storage temp.  2-8°C
form  crystal
color  yellow
λmax 380nm(CH2Cl2)(lit.)

Description and Uses

[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:

  • Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
  • Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
  • Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
  • Aryl-alkyl C?C reductive cross-coupling reactions.

Safety

Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
TSCA  No
HS Code  2843.90.0000

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